A node in a tree can have any number of branches. While a binary tree is a tree structure in which any node can have at most two branches. For binary trees we distinguish between the subtree on the left and subtree on the right, whereas for trees the order of the subtrees is irrelevant.
Consider two binary trees, but these binary trees are different. The first has an empty right subtree while the second has an empty left subtree. If the above are regarded as trees (not the binary trees), then they are same despite the fact that they are drawn differently. Also, an empty binary tree can exist, but there is no tree having zero nodes.